Nitride iodide
An iodide nitride is a mixed anion compound containing both iodide (I−) and nitride ions (N3−). Another name is metalloiodonitrides. They are a subclass of halide nitrides or pnictide halides.[1] Some different kinds include ionic alkali or alkaline earth salts, small clusters where metal atoms surround a nitrogen atom, layered group 4 element 2-dimensional structures (which could be exfoliated to a monolayer), and transition metal nitrido complexes counter-balanced with iodide ions. There is also a family with rare earth elements and nitrogen and sulfur in a cluster.
Related mixed-anion compounds include halogen variations: nitride fluoride, nitride chloride, and nitride bromide, and pnictogen variations phosphide iodide, arsenide iodide and antimonide iodides.
Production
Nitride iodides may be produced by heating metal nitrides with metal iodides. The ammonolysis process heats a metal iodide with ammonia.[2] A related method heats a metal or metal hydride with ammonium iodide. The nitrogen source could also be an azide or an amide.[2]
List
name | formula | formula weight | crystal system | space group | unit cell Å | volume | density | comments | ref |
---|---|---|---|---|---|---|---|---|---|
Li4NCl | hexagonal | R3 | a=366.225 c=1977.18 Z=3 | [3] | |||||
calcium nitride iodide | Ca2NI | P63/mmc | a = 3.8095, c = 14.530, Z = 2 | [4] | |||||
α-TiNI | orthorhombic | Pmmn | a=3.941 b=3.51.5 c=8.955 Z=2 | black | [5] | ||||
NCr(I)(NiPr2)2 | [6] | ||||||||
Cr(I)(N)(N(C(CD3)2CH3)(C6H3FMe))2 | [7] | ||||||||
Zn2NI | orthorhombic | Pnma | a=6.3590 b=6.2529 c=7.9549 | <6 GPa | [8] | ||||
strontium nitride iodide | Sr2NI | 316.15 | trigonal | R3m | a = 4.0049 c = 23.055 Z=3 | 320.24 | 4.918 | orange | [9] |
α-ZrNI | orthorhombic | Pmmn | a=4.114 b=3.724 c=9.431 Z=2 | orange | [10][5] | ||||
β-ZrNI | trigonal | R3m | a=3.718 c=31.381 Z=6 | brown | [5] | ||||
[(pcp)Mo(IV)(N)(I)][Na(15-crown-5)] pcp=C6H3(OPiPr2)2 | [11] | ||||||||
Ba2NI | |||||||||
LiLa4N2I7 | orthorhombic | Pnma | a = 13.7417, b = 12.1345, c = 10.7991 Z=4 | @100K | [12] | ||||
NaLa4N2I7 | orthorhombic | Pna21 | a=14.0018 b=10.9315 c=12.1021 Z=4 | 5.361 | colourless air sensitive | [13] | |||
Ce15N7I24 | 4245.6 | orthorhombic | Pnma | a=12.060 b=32.216 c=16.360 Z=4 | 5.48 | red; air sensitive | [14] | ||
NaCe4N2I7 | orthorhombic | Pna21 | a=13.9703 b=10.8932 c=12.0194 Z=4 | 5.446 | red air sensitive | [13] | |||
NaPr4N2I7 | orthorhombic | Pna21 | a=13.9412 b=10.8578 c=11.9389 Z=4 | 5.524 | yellowish green air sensitive | [13] | |||
NaNd4N2I7 | orthorhombic | Pna21 | a=13.9135 b=10.86 c=11.86 Z=4 | 5.638 | pinkish blue air sensitive | [13] | |||
(NdI2)3N | [15] | ||||||||
(NdI2)3N(DME)4 | [16] | ||||||||
NdI(S2N2)(THF) | [17] | ||||||||
Nd3I5(S2N2)(S2)(THF)10 | 2088.72 | monoclinic | P21 | a=12.393 b=43.389 c=12.684 β=90.013 Z=4 | 6820 | 2.034 | yellow | [15] | |
Ln3I5(S2)(S2N2)(THF)4(Phen)3 | [18] | ||||||||
Ln3I5(S2)(S2N2)(THF)3(Py)7 | [18] | ||||||||
(SmI)3N2(THF) | [16] | ||||||||
ErI(S2N2)(THF) | [17] | ||||||||
Nd2ErClI4-(S2)(S2N2)(THF)7 | [17] | ||||||||
Nd2ErCl2I3(S2)(S2N2)(THF)7 | [17] | ||||||||
(DyI2)3N | [19] | ||||||||
Dy3I5(S2)(S2N2)(THF)10 | [19] | ||||||||
Nd2DyI5(S2)(S2N2)(THF)7 | [17] | ||||||||
Nd2DyI5(S3)(S2N2)(THF)9 | 2034.88 | monoclinic | P21/c | a=23.1102 b=12.6551 c=23.8268 β =111.201 Z=4 | 6496.8 | 2.080 | [20] | ||
Nd2TbI5(S2)(S2N2)(THF)9 | monoclinic | P21/c | a =23.1704 b =12.6340 c =23.8340, β =111.274° Z=4 | [21] | |||||
Nd2TmI5(S2)(S2N2)(THF)9 | monoclinic | P21/c | a =23.075 b =12.6540 c =23.809, β =111.460° Z=4 | [21] | |||||
Nd2YbI5(S3)(S2N2)(THF)9 | monoclinic | P21/c | a=23.0959 b=12.6632 c=23.8387 β =111.363 Z=4 | 6493.0 | 2.092 | [20] | |||
α-HfNI | orthorhombic | Pmmn | a=4.10.67 b=3.6944 c=9.382 Z=2 | [5][10] | |||||
β-HfNI | trigonal | R3m | a=3.689 c=31.329 Z=6 | brown | [5] | ||||
ThNI | tetragonal | P4/nmm | a=4.107 c=9.242 | orange to golden grey | [5][22] | ||||
UNI | tetragonal | P4/nmm | a=3.99 c=9.20 Z=2 | [5][23] |
References
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- ^ Schurz, Christian M.; Niewa, Rainer; Schleid, Thomas (January 2020). "LiLa4N2I7 as the first lithium-containing nitride halide of the lanthanides: Synthesis, crystal structure and spectroscopic characterization". Solid State Sciences. 99: 106047. Bibcode:2020SSSci..9906047S. doi:10.1016/j.solidstatesciences.2019.106047. S2CID 209706784.
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- ^ Mattausch, Hansj Ürgen; Kremer, Reinhard K.; Simon, Arndt (April 1996). "Synthese, Kristallstruktur und magnetische Eigenschaften von Ce15N7I24". Zeitschrift für anorganische und allgemeine Chemie (in German). 622 (4): 649–654. doi:10.1002/zaac.19966220413. ISSN 0044-2313.
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- v
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HI +H | He | |||||||||||||||||
LiI | BeI2 | BI3 +BO3 | CI4 +C | NI3 NH4I +N | I2O4 I2O5 I2O6 I4O9 | IF IF3 IF5 IF7 | Ne | |||||||||||
NaI | MgI2 | AlI AlI3 | SiI4 | PI3 P2I4 +P PI5 | S2I2 | ICl ICl3 | Ar | |||||||||||
KI | CaI2 | ScI3 | TiI2 TiI3 TiI4 | VI2 VI3 | CrI2 CrI3 CrI4 | MnI2 | FeI2 FeI3 | CoI2 | NiI2 -Ni | CuI | ZnI2 | GaI GaI3 | GeI2 GeI4 +Ge | AsI3 As2I4 +As | Se | IBr IBr3 | Kr | |
RbI RbI3 | SrI2 | YI3 | ZrI2 ZrI3 ZrI4 | NbI4 NbI5 | MoI2 MoI3 | TcI3 | RuI3 | RhI3 | PdI2 | AgI | CdI2 | InI InI3 | SnI2 SnI4 | SbI3 +Sb | TeI4 +Te | I− I− 3 | Xe | |
CsI CsI3 | BaI2 | LuI3 | HfI3 HfI4 | TaI4 TaI5 | WI2 WI3 WI4 | ReI3 ReI 4 | OsI OsI2 OsI3 | IrI3 IrI 4 | PtI2 PtI4 | AuI AuI3 | Hg2I2 HgI2 | TlI TlI3 | PbI2 | BiI3 | PoI2 PoI4 | AtI | Rn | |
Fr | RaI2 | Lr | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
↓ | ||||||||||||||||||
LaI2 LaI3 | CeI2 CeI3 | PrI2 PrI3 | NdI2 NdI3 | PmI3 | SmI2 SmI3 | EuI2 EuI3 | GdI2 GdI3 | TbI3 | DyI2 DyI 3 | HoI3 | ErI3 | TmI2 TmI3 | YbI2 YbI3 | |||||
AcI3 | ThI2 ThI3 ThI4 | PaI4 PaI5 | UI3 UI4 | NpI3 | PuI3 | AmI2 AmI3 | CmI3 | BkI 3 | CfI 2 CfI 3 | EsI2 EsI3 | Fm | Md | No |